F Rosa Rubicondior: Far Beyond Carbon-Dating - A New Method for Building Timelines of Human Evolution

Sunday 2 May 2021

Far Beyond Carbon-Dating - A New Method for Building Timelines of Human Evolution

Fragments of ostrich eggshells from the Ysterfontein 1 site near Cape Town, South Africa. Researchers have determined that these eggshells are about 120,000 years old, discarded by early Homo sapiens who lived along the coast and exploiting marine food resources as well as ostrich eggs. The scale bar at lower right is 1 centimeter (0.4 inches).
Photo credit: Elizabeth Niespolo
Discarded ostrich shells provide timeline for our African ancestors | Berkeley News

Don't tell Creationist frauds like Ken Ham and Kent Hovind this, but scientists have found a way to extend the accuracy of precision radiometric dating of hominin activity to about 500,000 years - some ten times as far back as carbon-14 dating reliably takes us. It all depended on discarded ostrich shells from the midden tips of our African ancestors!

This holds out the possibility of accurately tracing the progress of our ancestors over time so giving us a more detailed picture of the timing and movement of the different archaic forms as they evolved.

A long and detailed news item from University of California at Berkeley (UC Berkeley) explains how, and the scientists' paper can be read in PNAS, sadly behind a paywall, so only the abstract and statement of significance is freely available.

Explaining the significance of their technique, the Berkeley team say:

Significance


Novel 230Th/U burial dating of ostrich eggshells complements other dating methods applicable to archaeological materials beyond the range of radiocarbon dating. New ages for the Ysterfontein 1 (YFT1) shell midden show it accumulated rapidly between ∼120 to 113 ka closely following the Last Interglacial sea-level highstand. The ages show the great antiquity of intensive human coastal adaptation, date a distinctive lithic industry, and show that teeth from YFT1 are among the oldest H. sapiens fossils recovered in southern Africa. Stable isotopes of ostrich eggshells indicate rapid cooling and drying during site occupation. Despite rapid sea-level drop and increasing aridity, the site’s occupants maintained a consistent diet, which may not indicate a stable paleoenvironment but rather results from systematic, selective foraging.
From the UC Berkeley News release:
The key to this dating technique that we have developed that differs from previous attempts to date ostrich egg shells is the fact that we are explicitly accounting for the fact that ostrich eggshells have no primary uranium in them, so the uranium that we are using to date the eggshells actually comes from the soil pore water and the uranium is being taken up by the eggshells upon deposition.

Elizabeth Niespolo, Lead author
Department of Earth and Planetary Science
University of California, Berkeley, CA USA;
and Berkeley Geochronology Center, Berkeley, CA USA
Archeologists have learned a lot about our ancestors by rummaging through their garbage piles, which contain evidence of their diet and population levels as the local flora and fauna changed over time.

One common kitchen scrap in Africa — shells of ostrich eggs — is now helping unscramble the mystery of when these changes took place, providing a timeline for some of the earliest Homo sapiens who settled down to utilize marine food resources along the South African coast more than 100,000 years ago.

Geochronologists at the University of California, Berkeley, and the Berkeley Geochronology Center (BGC) have developed a technique that uses these ubiquitous discards
The reason why this is exciting is that this site wouldn’t have been datable by radiocarbon because it is too old.

Almost all of this sort of site have ostrich eggshells, so now that we have this technique, there is this potential to go and revisit these sites and use this approach to date them more precisely and more accurately, and more importantly, find out if they are the same age as Ysterfontein or older or younger, and what that tells us about foraging and human behavior in the past.

The previous work to date eggshells with uranium series has been really hit and miss, and mostly miss.

Elizabeth Niespolo
to precisely date garbage dumps — politely called middens — that are too old to be dated by radiocarbon or carbon-14 techniques, the standard for materials like bone and wood that are younger than about 50,000 years.

In a paper published this month in the journal Proceedings of the National Academy of Sciences, former UC Berkeley doctoral student Elizabeth Niespolo and geochronologist and BGC and associate director Warren Sharp reported using uranium-thorium dating of ostrich eggshells to establish that a midden outside Cape Town, South Africa, was deposited between 119,900 and 113,100 years ago.

That makes the site, called Ysterfontein 1, the oldest known seashell midden in the world, and implies that early humans were fully adapted to coastal living by about 120,000 years ago. This also establishes that three hominid teeth found at the site are among the oldest Homo sapiens fossils recovered in southern Africa.

This is the first published body of data that shows that we can get really coherent results for things well out of radiocarbon range, around 120,000 years ago in this case. It is showing that these eggshells maintain their intact uranium-series systems and give reliable ages farther back in time than had been demonstrated before.

Warren D. Sharp, Co-author
Berkeley Geochronology Center, Berkeley, CA, USA
The technique is precise enough for the researchers to state convincingly that the 12.5-foot-deep pile of mostly marine shells — mussels, mollusks and limpets — intermixed with animal bones and eggshells may have been deposited over a period of as little as 2,300 years.

The new ages are already revising some of the assumptions archeologists had made about the early Homo sapiens who deposited their garbage at the site, including how their population and foraging strategies changed with changing climate and sea level.

“The reason why this is exciting is that this site wouldn’t have been datable by radiocarbon because it is too old,” Niespolo said, noting that there are a lot more such sites around Africa, in particular the coastal areas of South Africa.

Ysterfontein 1 (YFT1) is one of many middens along the Cape coast, some from the Middle Stone Age (white dots) and some from the more recent Later Stone Age (orange dots). The new dates for Ysterfontein 1 make it the oldest known midden in the world and helps put it in the context of the other sites as archeologists try to understand how early Homo sapiens lived and changed over the last 120,000 years.

Graphic: Elizabeth Niespolo

The new dates on ostrich eggshell and excellent faunal preservation make Ysterfontein 1 the as-yet best dated multi-stratified Middle Stone Age shell midden on the South African west coast. Further application of the novel dating method, where ostrich eggshell fragments are available, will strengthen chronological control in nearby Middle Stone Age sites, such as Hoedjiespunt and Sea Harvest, which have similar faunal and lithic assemblages, and others on the southern Cape coast.

Graham Avery, Co-author
Archeozoologist
Department of Natural History
Iziko Museums of South Africa, Cape Town, South Africa
“Almost all of this sort of site have ostrich eggshells, so now that we have this technique, there is this potential to go and revisit these sites and use this approach to date them more precisely and more accurately, and more importantly, find out if they are the same age as Ysterfontein or older or younger, and what that tells us about foraging and human behavior in the past,” she added.

Because ostrich eggshells are ubiquitous in African middens — the eggs are a rich source of protein, equivalent to about 20 chicken eggs — they have been an attractive target for geochronologists. But applying uranium-thorium dating — also called uranium series — to ostrich shells has been beset by many uncertainties.

“The previous work to date eggshells with uranium series has been really hit and miss, and mostly miss,” Niespolo said.

Precision dating pushed back to 500,000 years ago


Other methods applicable to sites older than 50,000 years, such as luminescence dating, are less precise — often by a factor of 3 or more — and cannot be performed on archival materials available in museums, Sharp said.
Middle Stone Age artifacts recovered from the Ysterfontein 1 midden include denticulates, points and red ochre (lower right).
Images: Richard Klein
The researchers believe that uranium-thorium dating can provide ages for ostrich eggshells as old as 500,000 years, extending precise dating of middens and other archeological sites approximately 10 times further into the past.

“This is the first published body of data that shows that we can get really coherent results for things well out of radiocarbon range, around 120,000 years ago in this case,” said Sharp, who specializes in using uranium-thorium dating to solve problems in paleoclimate and tectonics as well as archeology. “It is showing that these eggshells maintain their intact uranium-series systems and give reliable ages farther back in time than had been demonstrated before.”

“The new dates on ostrich eggshell and excellent faunal preservation make Ysterfontein 1 the as-yet best dated multi-stratified Middle Stone Age shell midden on the South African west coast,” said co-author Graham Avery, an archeozoologist and retired researcher with the Iziko South African Museum. “Further application of the novel dating method, where ostrich eggshell fragments are available, will strengthen chronological control in nearby Middle Stone Age sites, such as Hoedjiespunt and Sea Harvest, which have similar faunal and lithic assemblages, and others on the southern Cape coast.”

The first human settlements?


Ysterfontein 1 is one of about a dozen shell middens scattered along the western and eastern coasts of Western Cape Province, near Cape Town. Excavated in the early 2000s, it is considered a Middle Stone Age site established around the time that Homo sapiens were developing complex behaviors such as territoriality and intergroup competition, as well as cooperation among non-kin groups. These changes may be due to the fact that these groups were transitioning from hunter-gatherers to settled populations, thanks to stable sources of high-quality protein — shellfish and marine mammals — from the sea.

Photographs of marine shells and a schematic stratigraphy for the Ysterfontein 1 shell midden. The positions of ostrich eggshells used for dating and paleoenvironmental reconstruction are shown as egg symbols in the stratigraphic section.
Graphic: Elizabeth Niespolo
Until now, the ages of Middle Stone Age sites like Ysterfontein 1 have been uncertain by about 10%, making comparison among Middle Stone Age sites and with Later Stone Age sites difficult. The new dates, with a precision of about 2% to 3%, place the site in the context of well-documented changes in global climate: it was occupied immediately after the last interglacial period, when sea level was at a high, perhaps 8 meters (26 feet) higher than today. Sea level dropped rapidly during the occupation of the site — the shoreline retreated up to 2 miles during this period — but the accumulation of shells continued steadily, implying that the inhabitants found ways to accommodate the changing distribution of marine food resources to maintain their preferred diet.|

The study also shows that the Ysterfontein 1 shell midden accumulated rapidly — perhaps about 1 meter (3 feet) every 1,000 years -— implying that Middle Stone Age people along the southern African coast made extensive use of marine resources, much like people did during the Later Stone Age, and suggesting that effective marine foraging strategies developed early.

For dating, eggshells are better


Ages can be attached to some archeological sites older than 50,000 years through argon-argon (40Ar/39Ar) dating of volcanic ash. But ash isn’t always present. In Africa, however — and before the Holocene, throughout the Middle East and Asia — ostrich eggshells are common. Some sites even contain ostrich eggshell ornaments made by early Homo sapiens.

Over the last four years, Sharp and Niespolo, at the time a graduate student in UC Berkeley’s Department of Earth and Planetary Science, conducted a thorough study of ostrich eggshells, including analysis of modern eggshells obtained from an ostrich farm in Solvang, California, and developed a systematic way to avoid the uncertainties of earlier analyses. One key observation was that animals, including ostriches, do not take up and store uranium, even though it is common at parts-per-billion levels in most water. They demonstrated that newly laid ostrich shells contain no uranium, but that it is absorbed after burial in the ground.

The same is true of seashells, but their calcium carbonate structure — a mineral called aragonite — is not as stable when buried in soil as the calcite form of calcium carbonate found in eggshell. Because of this, eggshells retain better the uranium taken up during the first hundred years or so that that they are buried. Bone, consisting mostly of calcium phosphate, has a mineral structure that also does not remain stable in most soil environments nor reliably retains absorbed uranium.

Uranium is ideal for dating because it decays at a constant rate over time to an isotope of thorium that can be measured in minute amounts by mass spectrometry. The ratio of this thorium isotope to the uranium still present tells geochronologists how long the uranium has been sitting in the eggshell.

Uranium-series dating relies on uranium-238, the dominant uranium isotope in nature, which decays to thorium-230. In the protocol developed by Sharp and Niespolo, they used a laser to aerosolize small patches along a cross-section of the shell, and ran the aerosol through a mass spectrometer to determine its composition. They looked for spots high in uranium and not contaminated by a second isotope of thorium, thorium-232, which also invades eggshells after burial, though not as deeply. They collected more material from those areas, dissolved it in acid, and then analyzed it more precisely for uranium-238 and thorium-230 with “solution” mass spectrometry.

A cross-section of a fragment of an ancient eggshell from Ysterfontein 1 shows that the eggshell structures are well preserved, even though it was buried about 118,000 years ago. At the center is a pore that served as a pathway for oxygen for the incubating chick. Pitted lines are where the researchers used a laser to ablate portions of the eggshell to track concentrations of uranium and thorium and establish the age.

Image: Elizabeth Niespolo)
These procedures avoid some of the previous limitations of the technique, giving about the same precision as carbon-14, but over a time range that is 10 times larger.

“The key to this dating technique that we have developed that differs from previous attempts to date ostrich egg shells is the fact that we are explicitly accounting for the fact that ostrich eggshells have no primary uranium in them, so the uranium that we are using to date the eggshells actually comes from the soil pore water and the uranium is being taken up by the eggshells upon deposition,” Niespolo said.
No doubt, Creationists are now frantically working on a reason to rubbish this result and cast doubt on its accuracy, so they can continue to pretend real world data does not refute their childish creation myth and belief in a young earth. A belief they seem to hold for no better reason than that their mummy and daddy believed in it and told them that an ancient book about it was a science book, and if they didn't believe that, a magic, mind-reading sky boogie would be really angry and throw them in a pit of fire - because it loves them.


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