Abiogenesis News - Scientists Create Geothermal Vents In A Lab - And they Make Precursors For Life

A venting black smoker emits jets of particle-laden fluids. The particles are predominantly very fine-grained sulfide minerals formed when the hot hydrothermal fluids mix with near-freezing seawater. These minerals solidify as they cool, forming chimney-like structures. “Black smokers” are chimneys formed from deposits of iron sulfide, which is black. “White smokers” are chimneys formed from deposits of barium, calcium, and silicon, which are white.

Source: National Ocean Service.

Underwater thermal vents may have given rise to the first molecular precursors of life

A favourite disingenuous creationist tactic is to keep challenging science to achieve something that seems impossible—such as replicating the conditions of a deep ocean thermal vent to demonstrate that this could have been where life began. The trap is then to either gloat over science’s failure or to shift the goalposts and proclaim that any success merely proves that intelligence is required to create life.

So, we can almost guarantee that the news that a team of scientists at Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) in São Paulo, Brazil, have replicated not the thermal vents themselves but the chemical reactions believed to have occurred within them—and shown that these reactions do indeed produce the precursors of living systems—will be presented by creationists as supposed proof of the role of intelligence in the process.

The fallacy, of course, is that a laboratory experiment merely establishes the conditions under which natural forces can operate. By contrast, intelligent design advocates insist that an intelligent entity, working to a plan, must actively direct those natural forces to make chemistry and physics do something they supposedly couldn’t do on their own. Such is the intellectual dishonesty of many creationists that this distinction is either too subtle for them to grasp—or they deliberately ignore it.

Refuting Creationism - Clues to Abiogenesis In Japan's Hot Springs

A panoramic picture of one of five hot springs during winter, showing the source water and CO₂ bubbles.

Credit: Fatima Li-Hau, ELSI

Hot springs in Japan give insight into ancient microbial life on Earth – ELSI｜EARTH-LIFE SCIENCE INSTITUTE

It’s been a dreadful week for creationists as yet another published paper undermines one of their favourite claims and further reduces the god-shaped gap on which they increasingly depend — the so-called abiogenesis gap. This argument rests on the delusional assumption that if science has not yet fully explained something, then it never will — and therefore creationism wins by default. The history of science, of course, shows the opposite: today’s mysteries are tomorrow’s discoveries.

This time, the blow comes from a publication in the journal Microbes and Environments, which describes how five hot springs in Japan provide natural analogues of the conditions in which the first living organisms could have evolved. These springs are rich in diverse chemical and thermal gradients, making them excellent testbeds for exploring how life can thrive in extreme conditions and use non-traditional energy sources.

The study was conducted by a team led by Fatima Li-Hau, then a graduate student at the Earth-Life Science Institute (ELSI), Tokyo Institute of Science, with Associate Professor Shawn McGlynn as her supervisor. Their work focused on the microbial communities found in these hot springs, which range from moderately warm to boiling.

Refuting Creationism - Scarey Days For Creationists As More Signs of Life on Other Bodies Are Found

Artist's impression of Saturn's icy moon Enceladus. With a frozen surface covering a deep ocean, Enceladus is a fascinating target to search for signs of habitability elsewhere in our Solar System.

Graphic composition: ESA; Surface: NASA/JPL-Caltech/Space Science Institute/Lunar and Planetary Institute
(CC BY-SA 3.0 IGO)

An artist's depiction of water erupting from the "tiger stripe" fractures in the surface of Enceladus's south pole

© ESA.

ESA - Cassini proves complex chemistry in Enceladus ocean

In a soccer manager’s jargon, this is squeaky bum time for creationists who cling to the notion that science will never demonstrate that abiogenesis is even possible, let alone explain how it happened.

Squeaky bum time for a football manager is when the team’s league position — and with it qualification for European tournaments, and often the manager’s job — hangs on a single unpredictable result.

So it is with creationism. One single piece of definitive evidence that life has arisen independently on another world in the Solar System, or on an exoplanet orbiting a distant sun, would comprehensively consign creationism to the dustbin of history where it has been struggling to avoid ending up since 1859. Such a discovery would refute the claim that ‘life from non-life’ is impossible. Instead, it would show that under the right conditions, life is simply a natural product of chemistry and physics.

And the signs are as dire for creationism as for the embattled football team that finds itself 2–0 down in stoppage time. Scientists at the European Space Agency have just announced the detection of possible signs of life in the ocean beneath the icy crust of one of Saturn’s moons, Enceladus, as revealed by NASA’s Cassini spacecraft. This follows close on the heels of strong evidence that life once existed on Mars.

The tentative evidence from Enceladus points to processes in its subsurface ocean producing organic precursors to amino acids — the basic building blocks of proteins and a fundamental requirement for prebiotic chemistry that could eventually lead to organised cells. Researchers also report the detection of previously unknown molecules, including aliphatic and (hetero)cyclic compounds, esters, alkenes, ethers, and tentatively nitrogen- and oxygen-bearing compounds.

These organics were detected by Cassini’s Cosmic Dust Analyzer (CDA) in ice crystals ejected in plumes through cracks in Enceladus’ ice covering. These plumes are thought to form when water seeps into the moon’s rocky core, is heated, and then forced back up to the ocean floor as hydrothermal vents — much like those found in Earth’s oceans. The hot water increases the pressure in the subsurface ocean until the ice cracks and jets of vapour and ice crystals erupt. Most fall back to the surface, but some escape Enceladus’ weak gravity and contribute to one of Saturn’s rings, within which the moon orbits.

'Refuting Creationism - Scientists Have Found Strong Evidence of Life On Mars!

The Jezero Crater as it may have looked billions of years ago, when it was a lake.

Credit: NASA/JPL-Caltech

'Potential biosignatures' found in ancient Mars lake | Imperial News | Imperial College London

Scientists analysing data from NASA’s Perseverance rover have reported a tantalising discovery from Jezero Crater on Mars: rocks rich in minerals and chemical patterns that could represent potential biosignatures — the traces left behind by ancient life. The findings, published by an international team led from Imperial College London, point to the remains of an ancient lake where conditions may once have been favourable for microbial life to take hold.

The evidence comes from mudstones, clays, silica, iron-phosphate and iron-sulphide nodules, along with carbon compounds that appear to have undergone redox reactions. On Earth, such processes are often associated with biology, though the researchers are careful to stress that non-biological explanations are still possible. It will take the return of rock samples to Earth, with far more powerful laboratory techniques, before firm conclusions can be reached.

Abiogenesis News - UCL Scientists Show How LUCA Arose - No God(s) Required

Liquid brine veins, where RNA molecules can replicate, surround solid ice crystals in water ice, as seen with an electron microscope.

Credit: Philipp Holliger, MRC LMB

Graphic abstract

Attwater, J., Augustin, T.L., Curran, J.F. et al.(2025)

Chemists recreate how RNA might have reproduced for first time | UCL News - UCL – University College London

The day creationists dread — the final closure of their favourite god-shaped abiogenesis gap — moved a little closer last May, when scientists at University College London (UCL) announced that they had shown how the first RNA could have reproduced. In a selective environment with competition for resources, this would have led inevitably to ever-increasing efficiency in replication, kick-starting the whole evolutionary process and the emergence of self-organising systems (or “life”) from prebiotic precursors (or “non-life”). This is, of course, the very process that creationists insist is “impossible”, clinging to the idea that “life” is some magical essence that must be granted by a supernatural deity.

When this God-shaped gap is finally and conclusively closed — as all the others have been — creationists will need to scramble once again to reframe their beliefs and cling to whatever shrinking space remains for their god. Just as their old claim that evolution was “impossible” collapsed, to be replaced with notions of a short burst of warp-speed evolution “within kinds” after “The Flood” (and supposedly still happening today, but conveniently “guided” by God), so too will abiogenesis inevitably be rebranded as yet another process directed by divine intention — naturally, with the eventual production of (American) humans as the goal.

Refuting Creationism - The Real Universe is Nothing Like the One in the Bible

An optical image view of the Butterfly Nebula, NGC 6302, captured by the Hubble space telescope.

Credit: ESA/Webb, NASA & CSA, K. Noll, J. Kastner, M. Zamani (ESA/Webb)

This image, which combines infrared data from the James Webb Space Telescope with submillimetre observations from the Atacama Large Millimetre/submillimetre Array (ALMA), shows the doughnut-shaped torus and interconnected bubbles of dusty gas that surround the Butterfly Nebula’s central star. The torus is oriented vertically and nearly edge-on from our perspective, and it intersects with bubbles of gas enclosing the star. The bubbles appear bright red in this image, illuminated by the light from helium and neon gas. Outside the bubbles, jets traced by emission from ionised iron shoot off in opposite directions.

ESA/Webb, NASA & CSA, M. Matsuura, ALMA (ESO/NAOJ/NRAO), N. Hirano, M. Zamani (ESA/Webb) (CC BY 4.0).

An optical image view of the Butterfly Nebula, NGC 6302, captured by the Hubble space telescope.

Credit: ESA/Webb, NASA & CSA, K. Noll, J. Kastner, M. Zamani (ESA/Webb).

JWST observations of Butterfly Nebula reveal how cosmic dust is made in space - News - Cardiff University

There’s a double whammy for creationists in this new paper. Not only does it expose the Bible’s description of the Universe as laughably naïve, but it also shows how organic molecules — in the form of polycyclic aromatic hydrocarbons (PAHs) — that may have formed the basis of life on the prebiotic Earth, could have been created in deep space and later incorporated into our planet either at its formation or via impacts from space debris.

The paper, by a team of scientists led by Cardiff University, has just been published in Monthly Notices of the Royal Astronomical Society. Using data from the James Webb Space Telescope (JWST), the researchers reveal how stars generate space dust, organic material, and the fundamental building blocks from which rocky planets like Earth are formed. Their study focuses on the Butterfly Nebula (NGC 6302), a spectacular stellar remnant.

What Are PAHs?

Polycyclic aromatic hydrocarbons (PAHs) are complex organic molecules made of fused benzene rings — essentially arrangements of carbon and hydrogen in hexagonal patterns. On Earth, they are often associated with combustion (for example, in car exhaust fumes, cigarette smoke, or charred food). In space, however, they form naturally in the outflows of dying stars and in the dense molecular clouds that give rise to new stars and planetary systems.

PAHs are of great interest to astrobiologists because they are thought to be among the earliest organic compounds to have existed in the Universe. They can undergo chemical transformations to form more complex molecules, including amino acids and nucleotides, which are the essential components of life. Their presence in meteorites and interstellar dust suggests that the seeds of life were widespread long before Earth even formed.

Abiogenesis News - Fully Synthetic 'Life' Evolving in a Laboratory

Illustration showing the formation of new vesicles from the reorganization through self-reproduction of amphiphiles expelled into the bulk

S.K. Katla,C. Lin, & J. Pérez-Mercader (2025).

A step toward solving central mystery of life on Earth — Harvard Gazette

(A) Illustration showing the different stages of polymer vesicle growth leading to the action of expulsion of amphiphiles. (B) Illustration showing the formation of new vesicles from the reorganization through self-reproduction of amphiphiles expelled into the bulk.

S.K. Katla,C. Lin, & J. Pérez-Mercader (2025).

The frequent creationist assertion that abiogenesis is impossible without invoking supernatural intervention has taken another significant blow with the recent open‑access publication in Proceedings of the National Academy of Sciences (PNAS). The study, Self‑reproduction as an autonomous process of growth and reorganization in fully abiotic, artificial and synthetic cells, demonstrates, for the first time, the successful laboratory creation of simple, non‑biochemical self‑reproducing vesicle‑like systems exhibiting Darwinian evolution: each generation varies slightly in traits that influence their ability to replicate.

This breakthrough indicates that such self‑sustaining systems could plausibly arise through natural processes, and gradually—through Darwinian mechanisms—evolve into the first simple biological life forms, from which all life subsequently diversified. It also lends empirical support to the principle that when self‑replication with small variation occurs in a selective environment, evolution in the direction of increased fitness is inevitable.

Abiogenesis News - Organic Precursors to Life Detected In Deep Space.

Planet-forming disc around V883 Orionis. This star is currently in outburst. The dark ring midway through the disc is the point where the temperature and pressure dip low enough for water ice to form.
Orbits of the planet Neptune and dwarf planet Pluto in our Solar System are shown for scale.

Credit: ALMA (ESO/NAOJ/NRAO)/L. Cieza

This article is best read on a laptop, desktop, or tablet

This artist’s impression shows the planet-forming disc around the star V883 Orionis. In the outermost part of the disc volatile gases are frozen out as ice, which contains complex organic molecules. An outburst of energy from the star heats the inner disc to a temperature that evaporates the ice and releases the complex molecules, enabling astronomers to detect it. The inset image shows the chemical structure of complex organic molecules detected and presumed in the protoplanetary disc (from left to right): propionitrile (ethyl cyanide), glycolonitrile, alanine, glycine, ethylene glycol, acetonitrile (methyl cyanide).

© Credit: ESO/L. Calçada/T. Müller (MPIA/HdA) (CC BY 4.0)

The evolution of life may have its origins in outer space

If you listen to creationists, you might be persuaded to believe that the formation of inorganic chemicals—often deliberately conflated with 'life' to evoke an emotional reaction—is, for all practical purposes, impossible without the intervention of a supernatural intelligence. This is, of course, nothing more than the familiar creationist fallback: the god of the gaps argument, coupled with a false dichotomy, and dressed up with a spurious veneer of mathematical ‘proof’.

But this tactic suffered yet another fatal blow recently with the publication of a study led by Abubakar Fadul of the Max Planck Institute for Astronomy (MPIA), which reported the discovery of organic molecules in the protoplanetary disc surrounding the young star V883 Orionis. This finding provides compelling evidence that the formation of prebiotic molecules can begin even before planets form—suggesting that Earth may have developed with a complement of organic compounds already present in the accretion disc from which it emerged.

An alternative, but equally plausible, hypothesis is that these molecules could have been delivered by meteorites or other interplanetary bodies.

Refuting Creationism - The 'Abiogenesis Gap' Just Got a Little Bit Smaller

Image generated with Adobe Stock by Josef Kuster / ETH Zürich)

How urea forms spontaneously | ETH Zürich

Graphical representation of urea formation in a droplet.

Figure: Luis Quintero / ETH Zürich.

Creationism's ever-shrinking, gap-shaped creator god has just lost a little more ground. New research suggests that the formation of basic organic molecules may have been far easier under early Earth conditions than previously thought. Remarkably, scientists have found that urea—a key organic compound—can form spontaneously from ammonia and carbon dioxide on the surface of water droplets. This process requires no catalysts, no high pressure or heat, and consumes minimal energy.

Although vitalism was refuted as early as 1828 — decades before Darwin — creationists still claim that life cannot arise from non-living matter. Yet they quickly retreat when asked how dead food becomes living tissue, or what exactly they mean by ‘life’: a substance, a process, or some kind of magical force. In reality, life is a set of chemical processes, and at its core, it’s about managing entropy—using energy to maintain order against the natural drift toward disorder.

The discovery was made by researchers at Eidgenössische Technische Hochschule (ETH) Zürich in collaboration with colleagues from Auburn University in Alabama, USA. Their findings have just been published in Science.

Refuting Creationism - That Ever-Shrinking Little Creationist God Just Got Even Smaller

Liquid brine veins, where RNA molecules can replicate, surround solid ice crystals in water ice, as seen with an electron microscope.

Credit: Philipp Holliger, MRC LMB

Chemists recreate how RNA might have reproduced for first time | UCL News - UCL – University College London

The problem with having a god who exists merely to fill gaps in human knowledge and understanding — as the god of creationism does — is that science has been steadily shrinking those gaps ever since the scientific method emerged and the Church lost its power to persecute scientists for discovering inconvenient truths. Today, only a few small gaps remain, scattered throughout the body of scientific knowledge —particularly in biology, which holds special interest for creationists.

Creationism persists because there are still people with such a poor understanding of science that they believe the authors of ancient religious texts — written during the Bronze Age, when humanity's knowledge gaps encompassed nearly everything in their small world — had access to some deeper, divine insight. Although what they wrote is often naively simplistic and demonstrably wrong in almost every respect, creationists insist that it somehow surpasses anything modern science has produced in terms of accuracy and reliability.

One of the few remaining gaps where creationists attempt to place their god — the abiogenesis gap — has just shrunk further. Predictably, this will be ignored, dismissed, or misrepresented by creationist frauds who exploit carefully maintained ignorance to preserve their cult followings and income streams.

This discovery by chemists at University College London and the Medical Research Council Laboratory of Molecular Biology reveals how a simple RNA molecule can self-replicate under conditions thought to have existed on prebiotic Earth. Many scientists believe this marks the origin of RNA-based life, which eventually gave rise to the more complex protein- and DNA-based life we see today. A self-replicating RNA molecule, competing for limited resources, will naturally evolve to become more efficient — leaving more copies of itself than rival variants. This is classic Darwinian evolution, operating in a context Darwin himself could scarcely have imagined, knowing nothing of RNA or DNA.

The new research is published open access in Nature Chemistry.

Abiogenesis News - Closing Creationism's Favourite God-Shaped Gap - Still No God(s) Found

Diagram of an early cell membrane.

AI Generated image (ChatGPT4o)

How membranes may have brought about the chemistry of life on Earth | Department of Biology

Another hefty spadeful of science has just been shovelled into one of creationism’s favourite god-shaped gaps: the ever-shrinking mystery of abiogenesis. This is the gap that, through the intellectually dishonest tactic of the false dichotomy, creationists claim as evidence for their chosen deity.

Not only is this approach scientifically bankrupt, it also conveniently spares them the bother of providing any evidence or a testable mechanism of their own. For a target audience conditioned to see science as an attempt to disprove their god, the logic goes: if science is wrong—or even just incomplete—then “God did it!” wins by default.

But that dreaded moment for creationists, when science finally closes the gap and, like every other gap in history, finds no need for gods or magic in the explanation, draws ever nearer. The latest discovery bringing us closer comes in the form of new research into the origin and function of membranes—an essential step on the path from chemistry to life.

This particular piece of gap-filling comes from a paper published in PLOS Biology, authored by a team led by Professor Thomas Richards, Professor of Evolutionary Genomics in the Department of Biology at the University of Oxford. The researchers demonstrate that early cell membranes could not only have formed through natural processes, but also had the crucial ability to control what passed through them.

In doing so, they explain what had been something of a mystery and a favourite claim of ID creationists - the chirality of 'living' molecules where all amino acids have the same chirality. Creationists claim this shows the hand of an intelligent designer. This work shows it has a natural explanation.

Creationism Refuted - Science Has Found Evidence of Life On A Planet Outside the Solar System

Artist's impression of the exoplanet K2-18b.

Credit: A. Smith/N. Mandhusudhan

Artists light-hearted impression of life on K2-18b.

AI-generated image

Strongest hints yet of biological activity outside the solar system

The day long anticipated by those who understand both science and theology may finally have arrived. Scientists have detected—with a 99.7% probability—the unmistakable signs of life on the distant exoplanet K2-18b.

Although this degree of certainty doesn't yet satisfy the rigorous standards of science, which typically require a confidence level of greater than 99.99994%, researchers anticipate surpassing that threshold within the next 16 to 24 hours (as of this article's publication).

The theological implications of this discovery are profound. If confirmed, as now seems highly likely, it would indicate that Earth is not unique as a cradle of life, directly challenging biblical narratives which position Earth exclusively as the divinely chosen habitat for humanity. The Bible remains thoroughly anthropocentric and geocentric, offering no indication that life or divine creation occurred elsewhere in the comparatively small and flat universe it describes.

For creationists, this finding significantly undermines their long-standing argument—summarised by the simplistic slogan, "You can't get life from non-life"—which claims life could only arise through divine intervention. The presence of life on K2-18b demonstrates that life can indeed emerge naturally under the right conditions, suggesting such events may be far more common across the universe than creationist arguments would allow. Indeed, with potentially trillions of planets sharing Earth-like conditions, life may not only be possible but prevalent.

This discovery also challenges creationist claims about Earth's position in the so-called 'Goldilocks zone'. Creationists frequently argue that Earth's precise placement around the Sun proves divine intent. However, the existence of life-supporting conditions on K2-18b shows that such habitable zones are not rare, singular phenomena but commonplace, existing around countless other stars across the cosmos.

The discovery, by astronomers, led by the University of Cambridge, using data from the James Webb Space Telescope (JWST), is the subject of an open access paper in The Astrophysical Journal Letters and is described in a Cambridge University press release by Sarah Collins:

Abiogenesis News - Closing Another of Creationism's God-Shaped Gaps - Still No God Found

Formation of polyester protocells under early Earth-like conditions Polyester microdroplets, possible precursors to life, were formed from alpha-hydroxy acids (αHAs) in early Earth-like conditions even at low reaction volume, low reactant concentrations, and/or high NaCl or KCl concentrations.

Credit: Associate Professor Tony Z. Jia

How life’s building blocks took shape on early Earth: the limits of membraneless polyester protocell formation – ELSI｜EARTH-LIFE SCIENCE INSTITUTE

Creationism’ ever-shrinking little god that sits in the abiogenesis gap, just got smaller with the news that researchers led by PhD student Mahendran Sithamparam of the Space Science Center (ANGKASA), Institute of Climate Change, National University of Malaysia, working at the Earth-Life Science Institute (ELSI) in the Institute of Science, Tokyo, Japan, have shown how primitive protocells could have formed under a wide range of realistic probiotic Earth conditions. The research team included scientists from Taiwan and China.

The research showed that membraneless protocells could have formed by polymerization of alpha-hydroxy acids (αHAs) to form polyester microdroplets, not to be confused with the modern plastic polyester. These polymers were polymers of esters - simple organic compounds which are chemically similar to the monomers that make modern polyester fibres.

Refuting Creationism - First Steps to Abiogenesis

Diagram of the atmospheric evolution of Earth's ancient atmosphere estimated by this study

© Yoshida et al.

Research News - How Life Began on Earth: Modeling Earth's Ancient Atmosphere | Tohoku University Global Site

The fact that living organisms arose on Earth from inorganic sources rather than being made of nothing by magic, is an indisputable fact because there are living organisms on Earth and the chemicals they are composed of all exist on the planet in inorganic minerals and gases. 'Life' contains nothing that 'non-life' doesn't contain.

This much we know, but what we don't yet know and can probably never know with certainty, is precisely how and where that happen. In fact, we don't even know whether it did all start in the same place at the same time because the reason there are two different prokaryote cells - bacteria and archaea - could be because life arose on Earth not once but twice, by two different processes in two different places at two different times.

What we have though is lots of working hypotheses in the process of being validated.

What role would Earth's atmosphere have played in abiogenesis? Earth's early atmosphere was crucial in creating the right conditions for abiogenesis—the process by which life originated from non-living matter. While the exact composition of Earth’s primordial atmosphere is still debated, its unique conditions likely contributed in several essential ways:

1. Provision of Basic Building Blocks
   
   • Earth’s early atmosphere likely contained simple molecules like methane (CH₄), ammonia (NH₃), hydrogen (H₂), carbon dioxide (CO₂), nitrogen (N₂), and water vapor (H₂O). These molecules are rich in carbon, nitrogen, oxygen, and hydrogen—elements that are vital for organic compounds and, ultimately, for life.
   • When exposed to energy sources like ultraviolet (UV) radiation from the Sun or electrical discharges from lightning, these molecules could recombine into more complex organic molecules, such as amino acids and nucleotides, which are the building blocks of proteins and nucleic acids, respectively.
   
   
2. Facilitation of Prebiotic Chemistry
   
   • Experiments like the famous Miller-Urey experiment in 1953 showed that simple gases (methane, ammonia, hydrogen, and water vapor) in an atmosphere subjected to electrical sparks could produce amino acids. This suggests that Earth’s early atmosphere could have been instrumental in initiating chemical reactions that synthesized complex organic molecules.
   • Without a protective ozone layer, the early atmosphere allowed substantial UV radiation to penetrate the Earth’s surface, providing the energy necessary to drive these prebiotic reactions.
   
   
3. Supporting a Reducing Environment
   
   • The presence of reducing gases (such as methane and ammonia) would favor the formation of organic molecules because such conditions prevent the oxidation (and hence destruction) of organic compounds. Oxygen is highly reactive and can break down organic molecules, so the absence of free oxygen in the early atmosphere was likely a key factor that allowed these molecules to accumulate and react.
   • This reducing environment might have helped organic compounds to survive long enough to form stable, self-replicating systems.
   
   
4. Encouraging Geochemical Interactions
   
   • The interaction between the early atmosphere and the oceans, along with geothermal activity like volcanic eruptions and hydrothermal vents, provided a diverse range of chemical environments. In particular, hydrothermal vents may have supplied essential minerals and additional energy sources, further driving complex chemical reactions that are believed to be important in the formation of life.
   • The cycling of materials between the atmosphere and oceans would have contributed to creating localized "hotspots" for prebiotic reactions.
   
   
5. Protection and Concentration Mechanisms
   
   • The atmosphere also played a protective role by preventing the immediate dissipation of important compounds into space. It allowed the concentration of molecules and gases at Earth’s surface, increasing the chances of interactions among the essential precursors to life.
   • Early atmospheres may have helped regulate surface temperatures, preventing extreme fluctuations that would have been hostile to complex chemistry.
   
   
6. Encouraging Self-Organization and Membrane Formation
   
   • Interactions in the early atmosphere could have contributed to the formation of lipid molecules that could aggregate to form primitive cell-like structures or vesicles. These structures would eventually help in containing and protecting reactions necessary for early metabolic pathways.
   • These early "proto-cells" or vesicles would have been necessary to create a boundary for molecular interactions, which is a critical step toward the organization needed for cellular life.

In summary, Earth’s early atmosphere provided a chemically conducive, energetically rich environment that fostered the synthesis and concentration of organic molecules necessary for abiogenesis. This atmosphere also shielded these nascent molecules, allowing them to organize and evolve toward increasingly complex systems, eventually leading to the first living organisms.

One of which is the precise details of the atmosphere on the Early Earth, which is important because it would have had a major impact on the rest of the environment in which life arose. To gain a better understanding of that, a team from Tohoku University, Tokyo University and Hokkaido University, Japan, led by Tatsuya Yoshida have succeeded in modelling that atmosphere, as explained in a Tohoku University press release and published in the journal Astrobiology:

How Life Began on Earth: Modeling Earth's Ancient Atmosphere

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The key to unlocking the secrets of distant planets starts right here on Earth. Researchers at Tohoku University, the University of Tokyo, and Hokkaido University have developed a model considering various atmospheric chemical reactions to estimate how the atmosphere - and the first signs of life - evolved on Earth.

---

Ancient Earth was nothing like our current home. It was a much more hostile place; rich in metallic iron with an atmosphere containing hydrogen and methane.

Shungo Koyama, co-author
Graduate School of Science
Tohoku University, Sendai, Japan.

These molecules contain an important clue to how life was initially formed. When exposed to solar ultraviolet (UV) radiation, they undergo a chemical reaction that produces organics (also known as the "building blocks of life"). Part of these organics were precursors to essential biomolecules, such as amino acids and nucleic acids. However, understanding the role of UV radiation is difficult. Firstly, this type of atmosphere is unstable and likely underwent rapid changes due to atmospheric chemical reactions. Secondly, when UV radiation efficiently breaks down water vapour in the atmosphere and forms oxidative molecules, the precise branching ratio and timescale has not been determined. In order to address these issues, a 1D photochemical model was created to make accurate predictions about what the atmosphere was like on Earth long ago.

The calculation reveals that most hydrogen was lost to space and that hydrocarbons like acetylene (produced from methane) shielded UV radiation. This inhibition of UV radiation significantly reduced the breakdown of water vapour and subsequent oxidation of methane, thus enhancing the production of organics. If the initial amount of methane was equivalent to that of the amount of carbon found on the present-day Earth's surface, organic layers several hundred metres thick could have formed.

There may have been an accumulation of organics that created what was like an enriched soup of important building blocks. That could have been the source from which living things first emerged on Earth.

Tatsuya Yoshida, lead author
Graduate School of Science
Tohoku University, Sendai, Japan.

The model suggests that the atmosphere on ancient Earth was strikingly similar to what we see on current day neighbouring planets: Venus and Mars. However, despite their proximity, Earth evolved into a completely different environment. Researchers are trying to understand what makes Earth so special. As such, this model allows us to deepen our understanding of whether atmospheric evolution and the origin of life on Earth are unique or share common patterns with other planetary systems.

These findings were published in the journal Astrobiology on October 22, 2024.

Publication Details:

Tatsuya Yoshida, Shungo Koyama, Yuki Nakamura, Naoki Terada and Kiyoshi Kuramoto
Self-Shielding Enhanced Organics Synthesis in an Early Reduced Earth's Atmosphere Astrobiology DOI: 10.1089/ast.2024.0048

Abstract
Earth is expected to have acquired a reduced proto-atmosphere enriched in H₂ and CH₄ through the accretion of building blocks that contain metallic Fe and/or the gravitational trapping of surrounding nebula gas. Such an early, wet, reduced atmosphere that covers a proto-ocean would then ultimately evolve toward oxidized chemical compositions through photochemical processes that involve reactions with H₂O-derived oxidant radicals and the selective escape of hydrogen to space. During this time, atmospheric CH₄ could be photochemically reprocessed to generate not only C-bearing oxides but also organics. However, the branching ratio between organic matter formation and oxidation remains unknown despite its significance on the abiotic chemical evolution of early Earth. Here, we show via numerical analyses that UV absorptions by gaseous hydrocarbons such as C₂H₂ and C₃H₄ significantly suppress H₂O photolysis and subsequent CH₄ oxidation during the photochemical evolution of a wet proto-atmosphere enriched in H₂ and CH₄. As a result, nearly half of the initial CH₄ converted to heavier organics along with the deposition of prebiotically essential molecules such as HCN and H₂CO on the surface of a primordial ocean for a geological timescale order of 10–100 Myr. Our results suggest that the accumulation of organics and prebiotically important molecules in the proto-ocean could produce a soup enriched in various organics, which might have eventually led to the emergence of living organisms.

Yoshida, Tatsuya; Koyama, Shungo; Nakamura, Yuki; Terada, Naoki; Kuramoto, Kiyoshi
Self-Shielding Enhanced Organics Synthesis in an Early Reduced Earth’s Atmosphere Journal of Astrobiology (2024) DOI: 10.1089/ast.2024.0048

© 2024 Mary Ann Liebert, Inc.
Reprinted under the terms of s60 of the Copyright, Designs and Patents Act 1988.

So, by the action if UV radiation from the sun on the inorganic molecules in Earth's early atmosphere for a period of some 10-100 million years, the oceans could have accumulated the basic building blocks for organic organisms to get started, and all th result of chemistry and physics with no magic gods involved at any point.

And, as usual with scientific discoveries, the truth is shown to have little resemblance to the origin myths the parochial Bronze Age pastoralists made up to fill the yawning chasm in their knowledge and understanding of the world around them, with their belief that Earth had only existed for a few thousand years, so were blissfully ignorant of the 99.9975% of its history that occurred before then.

Refuting Creationism - LUCA Had Evolved 4.2 Billion Years Ago And Already Suffered From Viral Parasites

A digital representation illustrating how LUCA was already under attack from viruses even at 4.2 billion years ago.

Science Graphic Design

A digital representation illustrating how LUCA was already under attack from viruses even at 4.2 billion years ago.

Science Graphic Design

July: LUCA | News and features | University of Bristol

Contrary to the Bible's laughable model of a 10,000-year-old universe consisting of a small flat planet with a dome over it, containing nothing that was unknown to the Bronze Age hill farmers whose best guess became part of the Hebrew creation myth, scientists at the University of Bristol have shown that the last universal common ancestor of all living organisms (LUCA) had evolved within 400 million years of Earth forming some 4.6 billion years ago.

They have calculated that LUCA was about as complex as a prokaryote, had already evolved an immune system and was engaged in an arms race with viruses.

Abiogenesis News - RNA's Hidden Potential & Role In Early Cells

Ribozyme

RNA's Hidden Potential: New Study Unveils Its Role in Early Life and Future Bioengineering | Tokyo University of Science

In a recent open access paper in the online journal, Life, a Tokyo University of Science team led by Professor Koji Tamura of the Department of Biological Science and Technology, has given support to the 'RNA World' hypothesis that explains the beginnings of self-replicating organisms as self-catalysing RNA assemblies known as 'ribozymes'.

Ribozymes have the ability to catalyse the production of new ribozymes, so overcoming the 'problem' for abiogenesis that proteins are needed to catalyse the assembly of DNA but DNA is needed to create proteins, leading to a classic 'chicken and egg' paradox. Since ribozymes don't need proteins, this solves the problem.

How Professor Tamura' team did this is the subject of a Tokyo University of Science news release:

Creationism in Crisis - Closing The Last God-Shaped Gap - How The Simplest Cells Could Have Evolved, Naturally

Last Chance Lake in British Columbia

Credit: Zachary R. Cohen

Last Chance Lake in September 2022. At the end of the summer, the water has almost all evaporated, leaving a salty crust on the surface.

Credit: Zachary R. Cohen/Washington University

Did the first cells evolve in soda lakes?

According to a new study by Zachary R Cohen of the Chemistry Department of Washington University, Seatle, WA, USA and colleagues, soda lakes which are rich in sodium and carbonates could have provided the right conditions for the simplest, RNA-based cells to have arisen.

It is widely assumed that the earliest simple cells were based on RNA enclosed in a lipid membrane but there is a problem in that RNA requires divalent ions such as Magnesium (Mg²⁺ to function, but Mg²⁺ damages lipid membranes, so it isn't easy to explain how they could have co-existed within the same cell structure.

So the question is whether the low levels of (Mg²⁺ found in soda lakes, such as the Last Chance Lake in British Columbia, Canada, could have provided the right conditions of enough (Mg²⁺ for RNA to function but not so much as to prevent the formation of an enclosing membrane.

To explore this possibility, Zachary Cohen and his colleagues collected water from Last Chance Lake and the similar but subtly different Goodenough Lake after seasonal evaporation. According to information from Washington University published in phys.org:

These soda lakes each contained ~1 M Na⁺ and ~1 mM Mg²⁺ at pH 10. The authors found that spontaneous extension of short RNA primers occurred in lake water at a rate comparable to the rates in standard laboratory conditions.

The authors added fatty acids, which could have been available on the early Earth, to the lake water to see if the molecules would assemble into membranes. The membranes formed in dilute water that simulates a rainfall event, and the membranes persisted even when surrounded by concentrated lake water from the dry season.

According to the authors, soda lakes on the early Earth could have supported key features of protocell development, with RNA copying and ribozyme activity taking place in the dry season and vesicle formation occurring during the wet season.

The scientists give more technical details in their open access paper in PNAS Nexus:

Abiogenesis News - New Evidence For The 'RNA World' Hypothesis

Hammerhead sequences copied by the lower-fidelity polymerase drift away from their original RNA sequence (top) and lose their function over time. Hammerheads catalyzed by the higher-fidelity polymerase retain function and evolve fitter sequences (bottom).

Credit: Salk Institute

Stylized rendering of the full-length hammerhead ribozyme RNA molecule

Source: Wikipedia

Modeling the origins of life: New evidence for an “RNA World” - Salk Institute for Biological Studies

On way of looking at cellular life is that it is based on RNA, not DNA. In that model, DNA is RNA's data store. All the functional processes that DNA codes for are first transcribed into RNA and short lengths of RNA still regulate some of the cell processes. RNA can even act as a catalyst playing the role normally performed by protein enzymes - proteins that are themselves transcriptions of RNA triplet codes for amino acid sequences.

On that model, early self-replicating systems were based on RNA, and DNA was late to the game.

Now three researchers at the Salk Institute for Biological Studies, La Jolla, California, USA, have shown how such a system could have bootstrapped from simple, self-catalysing lengths of RNA which not only self-replicate but can continue to do so even when there are variations stemming from faulty replications. This system would have created the variation needed for Darwinian evolution by natural selection as some variant performed better in terms of competing for resources and ultimately making more copies, so coming to predominate in the pool of RNA-based organisms.

How the scientists discovered this is the subject of a research paper in PNAS which sadly is behind a paywall with only the abstract and statement of significance freely available. It is also the subject of a news release from the Salk Institute.

Since the team refer to an RNA structure known as the 'hammerhead ribozyme', it might help to understand a little about it first:

Abiogenesis News - That God-Shaped Gap Just Keeps On Shrinking

Scripps Research scientists reveal how first cells could have formed on Earth | Scripps Research

It's been a bad week so far for creationists. Coming so soon after scientist announced they had solved the 'chirality problem, is news that another team have shown how simple cells could plausibly have formed in the pre-biotic conditions that pertained on early Earth.

Creationists are generally black & white thinkers who value certainty above truth, so, for them there is no such thing as a plausible explanation; either something is proven beyond doubt, even passing an especially impossible standard of evidence, or it is wrong (so God did it!).

And one of their 'certainties' is their absolute faith in the slogan, "You can't get life from non-life!", which is chanted like a protective mantra in any debate about evolution (conveniently switching the debate from evolution to what they think is safer ground, abiogenesis). But ask them to define 'life' in such a way that you can test for it to tell if something is alive or not, or to explain how the non-living food they eat gets converted into living tissues, if that's impossible, and you're likely to get an ad hominem or an indignant, condescending flounce and a swift termination of the conversation.

It is an essential ingredient of creationism that the belief that abiogenesis is 'impossible' be maintained as the last refuge for their ever-shrinking creator god to be located in, as all the other gaps are closed to it.

So, having committed themselves to the certainty that abiogenesis is 'impossible', they have unwittingly committed themselves to accepting that any plausible process which can be shown to be viable, refutes the notion of impossibility and everything they conclude from it. So, their next step is the intellectually bankrupt technique of moving the goal-posts or demanding scientist provide an impossible standard of evidence such as showing it happening - billions of years ago. Never will they concede that evidence of plausibility refutes the claim of impossibility because, to a black & white thinker, plausibility doesn't give enough certainty, so can be dismissed until proven.

So, we can expect that predictable display of intellectual bankruptcy in response to the news that scientists at the Scripps Institute, La Jolla, CA, USA have discovered a plausible mechanism for the formation of simple self-replicating cells in the prebiotic conditions that pertained on early Earth.

Their findings are published in the Cell Press journal Chem and are the subject of a Cripps Institute press release:

Creationism in Crisis - Biological Chirality Explained - And Another Favourite Creationist Gap Slams Shut With No God(s) Found

How molecular “handedness” emerged in early biology | Scripps Research

Back in the 1980's when I first encountered (mostly) American creationists on the emerging Internet, one of their arguments from personal incredulity was that 'no-one can explain' why amino acids occur naturally in two stereo forms, yet only one is found in nature (therefore God did it!).

This 'problem' for evolutionary biologist now seems to have dropped out of favour with creationists, probably because, as more and more former creationists realise they've been fooled, only the lower tail-end of the IQ bell curve remain, and this phenomenon, known as chirality, is a little difficult to understand and requires a modicum of understanding of chemistry.

Basically, at the heart of an amino acid is a carbon atom with four different atoms of groups attached. This structure can be thought of as a pyramid with a triangular base (known as a tetrahedron) with the carbon atom in the centre and each of the four atoms or groups at each point of the tetrahedron. These groups can be attached to the carbon in two separate ways so that one is a mirror image of the other. These are known as chiral forms or stereo-isomers. No matter how you rotate one, it can never be the same as its opposite chiral form.

These chiral forms have the same chemical properties and the same physical properties apart from one - the way they interact with polarised light. One form causes the plane of polarity of polarised light to rotate in one direction, the other in the other direction; so they are also known as optical isomers.

The chiral forms of amino acids are prefixed with 'D' or 'L' (upper case; Dextro and Laevo (right and left)) according to the physical structure, or 'd' and 'l' (lower case) according to which direction they rotate the plane of polarity of polarized light.

ChatGPT explains it more succinctly: